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Friday, 26 July 2013

Mass Spectra Interpretation: ALDEHYDES

Mass Spectra Interpretation: ALDEHYDES

No. of Questions= 8
ELECTRON IMPACT MASS SPECTROMETRY PRODUCED THE SPECTRA BELOW. MANY PEAKS ARE LABELLED TO AID INTERPRETATION: M/Z (RELATIVE ABUNDANCE). LOOK AT THE HINTS AND FOLLOW THE WEB REFERENCE LINK FOR HELP. YOU WILL NEED A PERIODIC TABLE, A TABLE OF COMMON ISOTOPES (WHICH YOU CAN FIND IN THE WEB REFERENCE), A CALCULATOR, AND SCRATCH PAPER TO WORK THIS QUIZ.

1 How many oxygens are in the molecular ion peak in this spectrum?


      Web Reference      


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a) 0

b) 1

c) 2



2 For this same spectrum, choose the compound that the spectrum represents.


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a) butanal

b) propanal

c) 2-propenal

d) methoxy-ethene

e) ethanediol



3 Find the alkyl ion series in the spectra below. (Check the hint!)


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a) 15, 29, 43

b) 29, 43, 57

c) none



4 Find the alkyl LOSS ion series in the same spectra shown below. (Check the hint!)


      Web Reference      


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a) 15, 29, 43

b) 29, 43, 57

c) none



5 For this same spectrum, choose the compound that the spectrum represents.


      Web Reference      


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a) 2-propenal

b) 2-methyl propanal

c) pentanal

d) 2-oxo-propanal

e) butanal



6 Choose the compound that this spectrum represents.


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a) hexanal

b) 3-methyl butanal

c) pentanal

d) 2-methyl propanal

e) 2,2-dimethyl propanal



7 Choose the compound that this spectrum represents.


      Web Reference      


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a) 2-methyl propanal

b) butanal

c) 2-oxo-propanal

d) 2-propenal

e) pentanal



8 Choose the compound that this spectrum represents.


      Web Reference      


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a) 2,2-dimethyl propanal

b) hexanal

c) 2-oxo-propanal

d) 3-methyl-butanal

e) pentanal

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