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Sunday 21 April 2013

SP3 HYBRIDIZATION OF CARBON

In sp3 hybridization, one 2s and three 2p orbitals of excited carbon intermix together and form 4 hybrid orbitals which are oriented in tetrahedral geometry in space around the carbon atom. Each sp3 hybrid orbital is occupied by one electron.
sp3 hybridization of carbon
Each of these sp3 orbitals can form σ-bond with other atom. Thus carbon is forming four single bonds with other atoms in tetrahedral geometry. The bond angles are usually equal to or nearer to 109o28'.
E.g. In methane molecule, CH4, the carbon atom undergoes sp3 hybridization and forms four σ-bonds with hydrogen atoms.
Note that whenever carbon atom undergoes sp3 hybridization, it forms 4 σ-bonds i.e., 4 single bonds.

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